Mix flour and butter in stand mixer until crumbly. Add sour cream and mix just until a dough forms.
Wrap and chill for 1 hour.
Boil water and butter; stir in sugar until dissolved. Add vanilla and nuts. Once cooled slightly, stir in egg white.
Roll dough on powdered sugar to ⅛-inch thick. Cut into 2¼-inch squares.
Place nut filling diagonally and fold corners over.
Bake at 350°F for 13–15 minutes. Cool on rack.